Site-inversion versus frustration in the CoAl$_2$O$_4$ spinel: A neutron diffraction study at MURR

COFFEE_KLATCH · Invited

Abstract

Neutron diffraction studies of a well defined CoAl$_2$O$_4$ polycrystalline sample reveal the role that site-inversion plays in determining the magnetic properties of this system. The A-B site-inversion in the spinel system is a long standing issue. In this regard CoAl$_2$O$_4$ is notorious as Co-Al site-inversion can exceed 20\% and, so far, could not be totally eliminated. In this talk, I will review previous reports including more recent ones that emphasize Co-Co next-nearest-neighbor coupling in the diamond-like Co sublattice that is claimed to lead to exotic spin-liquid structure or to be on the boundary of a recently predicted phase diagram between a collinear antiferromagnetic and a spiral magnetic structure. I will present the various views on the phase diagram of CoAl$_2$O$_4$ as a function of Co-Al site inversion parameter and contrast them with our neutron diffraction studies.

Authors

  • David Vaknin

    Ames Laboratory and Department of Physics and Astronomy, Iowa State University, Ames IA 50011