Rotational Spectroscopy of the Excited States of Nitric Acid

ORAL

Abstract

Because it is an important molecular species in the ozone cycle in the upper atmosphere, nitric acid (HNO3) has been the subject of many studies in both the infrared and in the microwave region of the spectrum. Our microwave studies of the rotational spectrum of nitric acid now includes work on all of the excited states below 1200 cm-1 in energy as well a few states at higher energy, such as the v2 state at 1700 cm-1. Microwave studies of the rotational spectrum of HNO3 in excited vibration states contribute both to a better understanding of this fundamental molecule and to the construction of accurate spectral maps for infrared remote sensing. An overview of our studies of the rotational spectroscopy of the excited states will be presented, including our observation of torsion splitting in a number of states. Our recent progress on the assignment and analysis of transitions other states will also be presented.

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Authors

  • Paul Helminger

    University of South Alabama

  • J. Deng

    US Naval Observatory, University of Virginia, Thomas Jefferson National Accelerator Facility, College of William and Mary, US Army Research Office, Brimrose Corporation of America, Hampton University, Department of Physics, University of Rajshahi, Rajshahi, Bangladesh, Department of Physics, Old Dominion University, Norfolk, VA 23529, University of North Carolina at Chapel Hill, Department of Physics, Old Dominion University, Norfolk, Virginia, Department of Physics, Korea University, Seoul, Korea, Department of Physics, University of Virginia, Charlottesville, VA, Department of Physics, Old Dominion University, Norfolk, VA, North Carolina State University and WebAssign, Raleigh, NC, North Carolina State University, Raleigh, NC, Broughton High School, Raleigh, NC, University of Wisconsin at Whitewater, Whitewater, WI, University of North Carolina-Chapel Hill Department of Physics, University of West Virginia - Chemistry Dept., ORNL, Old Dominion University, University of West Virginia Department of Chemistry, Clemson University, South Carolina Governor’s School for Science and Mathematics, College of Charleston, Rice University, Korea Research Institute of Standards and Science, Ohio State University, Wright State University, Yale U, JINR, Dubna, Univ. Fed. do Rio de Janeiro, Vanderbilt Univ./JIHIR(ORNL)/Tsinghua Univ., NSCL(MSU), LLNL, LBNL, Vanderbilt Univ./LBNL/JIHIR(ORNL), Vanderbilt Univ., Jagellonian University, University of Bonn, North Carolina A{\&T} State University, North Carolina Central University, Duke University and TUNL

  • J. Deng

    US Naval Observatory, University of Virginia, Thomas Jefferson National Accelerator Facility, College of William and Mary, US Army Research Office, Brimrose Corporation of America, Hampton University, Department of Physics, University of Rajshahi, Rajshahi, Bangladesh, Department of Physics, Old Dominion University, Norfolk, VA 23529, University of North Carolina at Chapel Hill, Department of Physics, Old Dominion University, Norfolk, Virginia, Department of Physics, Korea University, Seoul, Korea, Department of Physics, University of Virginia, Charlottesville, VA, Department of Physics, Old Dominion University, Norfolk, VA, North Carolina State University and WebAssign, Raleigh, NC, North Carolina State University, Raleigh, NC, Broughton High School, Raleigh, NC, University of Wisconsin at Whitewater, Whitewater, WI, University of North Carolina-Chapel Hill Department of Physics, University of West Virginia - Chemistry Dept., ORNL, Old Dominion University, University of West Virginia Department of Chemistry, Clemson University, South Carolina Governor’s School for Science and Mathematics, College of Charleston, Rice University, Korea Research Institute of Standards and Science, Ohio State University, Wright State University, Yale U, JINR, Dubna, Univ. Fed. do Rio de Janeiro, Vanderbilt Univ./JIHIR(ORNL)/Tsinghua Univ., NSCL(MSU), LLNL, LBNL, Vanderbilt Univ./LBNL/JIHIR(ORNL), Vanderbilt Univ., Jagellonian University, University of Bonn, North Carolina A{\&T} State University, North Carolina Central University, Duke University and TUNL

  • J. Deng

    US Naval Observatory, University of Virginia, Thomas Jefferson National Accelerator Facility, College of William and Mary, US Army Research Office, Brimrose Corporation of America, Hampton University, Department of Physics, University of Rajshahi, Rajshahi, Bangladesh, Department of Physics, Old Dominion University, Norfolk, VA 23529, University of North Carolina at Chapel Hill, Department of Physics, Old Dominion University, Norfolk, Virginia, Department of Physics, Korea University, Seoul, Korea, Department of Physics, University of Virginia, Charlottesville, VA, Department of Physics, Old Dominion University, Norfolk, VA, North Carolina State University and WebAssign, Raleigh, NC, North Carolina State University, Raleigh, NC, Broughton High School, Raleigh, NC, University of Wisconsin at Whitewater, Whitewater, WI, University of North Carolina-Chapel Hill Department of Physics, University of West Virginia - Chemistry Dept., ORNL, Old Dominion University, University of West Virginia Department of Chemistry, Clemson University, South Carolina Governor’s School for Science and Mathematics, College of Charleston, Rice University, Korea Research Institute of Standards and Science, Ohio State University, Wright State University, Yale U, JINR, Dubna, Univ. Fed. do Rio de Janeiro, Vanderbilt Univ./JIHIR(ORNL)/Tsinghua Univ., NSCL(MSU), LLNL, LBNL, Vanderbilt Univ./LBNL/JIHIR(ORNL), Vanderbilt Univ., Jagellonian University, University of Bonn, North Carolina A{\&T} State University, North Carolina Central University, Duke University and TUNL

  • J. Deng

    US Naval Observatory, University of Virginia, Thomas Jefferson National Accelerator Facility, College of William and Mary, US Army Research Office, Brimrose Corporation of America, Hampton University, Department of Physics, University of Rajshahi, Rajshahi, Bangladesh, Department of Physics, Old Dominion University, Norfolk, VA 23529, University of North Carolina at Chapel Hill, Department of Physics, Old Dominion University, Norfolk, Virginia, Department of Physics, Korea University, Seoul, Korea, Department of Physics, University of Virginia, Charlottesville, VA, Department of Physics, Old Dominion University, Norfolk, VA, North Carolina State University and WebAssign, Raleigh, NC, North Carolina State University, Raleigh, NC, Broughton High School, Raleigh, NC, University of Wisconsin at Whitewater, Whitewater, WI, University of North Carolina-Chapel Hill Department of Physics, University of West Virginia - Chemistry Dept., ORNL, Old Dominion University, University of West Virginia Department of Chemistry, Clemson University, South Carolina Governor’s School for Science and Mathematics, College of Charleston, Rice University, Korea Research Institute of Standards and Science, Ohio State University, Wright State University, Yale U, JINR, Dubna, Univ. Fed. do Rio de Janeiro, Vanderbilt Univ./JIHIR(ORNL)/Tsinghua Univ., NSCL(MSU), LLNL, LBNL, Vanderbilt Univ./LBNL/JIHIR(ORNL), Vanderbilt Univ., Jagellonian University, University of Bonn, North Carolina A{\&T} State University, North Carolina Central University, Duke University and TUNL