The Excited States of Nitric Acid: Recent Results

ORAL

Abstract

Because nitric acid is an important molecular species in the ozone cycle in the upper atmosphere, it has been the subject of many studies in both the infrared and microwave regions of the spectrum. Microwave studies of the rotational spectrum of nitric acid in excited vibration states contribute both to a better understanding of this fundamental molecule and to the construction of accurate spectral maps for infrared remote sensing. We have recently completed work on the rotational spectrum of the interacting v6+v7 and v8+v9 states of nitric acid. The results of this work will be discussed. Our recent progress on the interacting v3 and v4 states will also be presented. Our microwave studies of the rotational spectrum of nitric acid now includes work on all of the excited states below 1250 cm$^{-1}$ in energy as well as the v2 state at 1700 cm$^{-1}$.

Authors

  • Paul Helminger

    University of South Alabama

  • Rebecca Scott

    UCSB, LBNL, NCSU, University of North Carolina at Chapel Hill, Wright State University, Department of Physics, The University of Memphis, TN 38152, North Carolina State University, Department of Chemical and Biomolecular Engineering, Raleigh, NC, Clemson University, Fisk University, University of North Dakota (Grand Forks), Southern Illinois University, The University of Tennessee Space Institute, SC Governor's School for Science and Mathematics, Francis Marion University, University of North Alabama, Lousiana State University, Department of Physics, Dhaka University, Dhaka, Bangladesh, Head of Government Relations, American Physical Society, Vanderbilt University, Mississippi State University, Emory University, College of William and Mary, University of Tennessee Space Institute, Morehead State University

  • Rebecca Scott

    UCSB, LBNL, NCSU, University of North Carolina at Chapel Hill, Wright State University, Department of Physics, The University of Memphis, TN 38152, North Carolina State University, Department of Chemical and Biomolecular Engineering, Raleigh, NC, Clemson University, Fisk University, University of North Dakota (Grand Forks), Southern Illinois University, The University of Tennessee Space Institute, SC Governor's School for Science and Mathematics, Francis Marion University, University of North Alabama, Lousiana State University, Department of Physics, Dhaka University, Dhaka, Bangladesh, Head of Government Relations, American Physical Society, Vanderbilt University, Mississippi State University, Emory University, College of William and Mary, University of Tennessee Space Institute, Morehead State University

  • Frank C. De Lucia