The Terahertz Spectrum of the v5/2v9 Dyad of Nitric Acid

ORAL

Abstract

Because nitric acid is an important molecular species in the ozone cycle in the upper atmosphere, it has been the subject of many studies in both the infrared and microwave regions of the spectrum. Microwave studies of the rotational spectrum of nitric acid in excited vibration states contribute both to a better understanding of this fundamental molecule and to the construction of accurate spectral maps for remote sensing. Our most recent work on nitric acid includes studies of the terahertz spectrum of the ground state and four lowest-energy excited vibrational states. We have now extended this work to include measurements and analysis of the rotational transitions of the v5/2v9 dyad of nitric acid. This very complex spectrum includes torsional splitting of both states and Fermi and Coriolis type interactions between them. Preliminary results of the assignment and analysis will be reported.

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Authors

  • Paul Helminger

    University of South Alabama

  • Philip Adams

    Department of Physics and Astronomy, Louisiana State University, ORNL, UT, ORNL/UT, UK, LSU, Louisiana State University, Zhejiang Normal University, Center for Computation and Technology, Louisiana State University, University of Tuebingen, Germany, Aristotle University of Thessaloniki, Greece, Max Planck Institute for Astrophysics, Max Plank Institute for Astrophysics, Laboratoire d'Astrophysique de Marseille, Albert Einstein Institute, California Institute of Technology, Dept. of Physics \& Astronomy, Louisiana State University, Baton Rouge, LA 70803, Dept. of Physics \& Astronomy, Louisiana State Univ., Baton Rouge, LA 70803, NASA Marshall Space Flight Center, Dept. of Physics \& Astronomy, Louisiana State University, Ohio State University, Wright State University, Department of Physics, North Carolina A\&T State University, Clark Atlanta University, Department of Electrical and Computer Engineering, Pennsylvania State University, University Park, P, Princeton University, University of New Orleans, Alabama A\&M University, Vanderbilt Univ., Konstanz Univ., Isik Univ., Department of Physics, Yale University

  • Philip Adams

    Department of Physics and Astronomy, Louisiana State University, ORNL, UT, ORNL/UT, UK, LSU, Louisiana State University, Zhejiang Normal University, Center for Computation and Technology, Louisiana State University, University of Tuebingen, Germany, Aristotle University of Thessaloniki, Greece, Max Planck Institute for Astrophysics, Max Plank Institute for Astrophysics, Laboratoire d'Astrophysique de Marseille, Albert Einstein Institute, California Institute of Technology, Dept. of Physics \& Astronomy, Louisiana State University, Baton Rouge, LA 70803, Dept. of Physics \& Astronomy, Louisiana State Univ., Baton Rouge, LA 70803, NASA Marshall Space Flight Center, Dept. of Physics \& Astronomy, Louisiana State University, Ohio State University, Wright State University, Department of Physics, North Carolina A\&T State University, Clark Atlanta University, Department of Electrical and Computer Engineering, Pennsylvania State University, University Park, P, Princeton University, University of New Orleans, Alabama A\&M University, Vanderbilt Univ., Konstanz Univ., Isik Univ., Department of Physics, Yale University

  • Philip Adams

    Department of Physics and Astronomy, Louisiana State University, ORNL, UT, ORNL/UT, UK, LSU, Louisiana State University, Zhejiang Normal University, Center for Computation and Technology, Louisiana State University, University of Tuebingen, Germany, Aristotle University of Thessaloniki, Greece, Max Planck Institute for Astrophysics, Max Plank Institute for Astrophysics, Laboratoire d'Astrophysique de Marseille, Albert Einstein Institute, California Institute of Technology, Dept. of Physics \& Astronomy, Louisiana State University, Baton Rouge, LA 70803, Dept. of Physics \& Astronomy, Louisiana State Univ., Baton Rouge, LA 70803, NASA Marshall Space Flight Center, Dept. of Physics \& Astronomy, Louisiana State University, Ohio State University, Wright State University, Department of Physics, North Carolina A\&T State University, Clark Atlanta University, Department of Electrical and Computer Engineering, Pennsylvania State University, University Park, P, Princeton University, University of New Orleans, Alabama A\&M University, Vanderbilt Univ., Konstanz Univ., Isik Univ., Department of Physics, Yale University