NMR study of $^{133}$Cs in new quasi-one-dimensional conducting platinate

ORAL

Abstract

Cs$_{4}$[Pt(CN)$_{4}$](CF$_{3}$SO$_{3})_{2}$ (TCP) is a new Krogmann's salt, consisting of quasi-one-dimensional conducting chains of Pt with well known properties, especially in the potassium-containing material, KCP. Unlike KCP, however, there are properties unique to TCP, e.g., longer Pt-Pt separation, insulating at room temperature, and non-magnetic. Previous NMR studies on KCP have mainly been on $^{195}$Pt, which does not produce a usable NMR signal in TCP; our study utilizes $^{133}$\textbf{Cs} instead, which are peripheral to the Pt chains. Splitting of spin states due to quadrupole interaction with local electric field gradient has been measured as a function of orientation versus applied static field. Modeling of the frequency shifts reveals consistency with the known symmetry axes of $^{133}$\textbf{Cs} determined by single-crystal x-ray diffraction. Relaxation time T1 versus temperature reveals a weak relaxation mechanism and absence of magnetism. Relaxation data has a sharp anomaly around 119 K where T1 jumps 3 orders of magnitude, consistent with critical fluctuations but not yet well understood.

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Authors

  • R.I. Leatherbury

    U. of South Alabama Dept. of Physics

  • J. Alexander

    U. of South Alabama Dept. of Physics

  • O. Gafarov

    U. of South Alabama Dept. of Physics

  • A.A. Gapud

    U. of South Alabama Dept. of Physics, U. of South Alabama Dept of Physics, University of South Alabama

  • Rahul Kulkarni

    Materials and Structures Laboratory, Tokyo Institute of Technology, Jefferson Lab, 12000 Jefferson Avenue, MS 58, Suite 17, Newport News, VA 23606, VirginiaTech, Department of Physics, University of South Alabama, New York University, University of Tennessee Knoxville, Georgia College, North Georgia College \& State Univ., North Carolina Central University, TUNL, James Madison University, Physics Department, Hollins University; JQI, University of Aarhus, University of Tennessee, UNC at Asheville, The College of New Jersey, CERN, Florida Institute of Technology, Mechanical Engineering Department, University of New Mexico, Department of Physics, Florida State University, JINR, Vanderbilt, Tsinghua University, LBNL, Vanderbilt and LBNL, Vanderbilt University, Vanderbilt University, Tsinghua University, Vanderbilt University, LBNL, NBPHS, Vanderbilt University, Dept. of Physics and Astronomy - James Madison University, National High Magnetic Field Laboratory, U. of South Alabama Dept. of Chemistry, U. of South Alabama Dept. of Physics, Ohio State University, Wright State University, Engineering Science and Mechanics, Virginia Tech, US, Department of Nanobio Materials and Electronics, GIST, Republic of Korea, Department of Physics, Virginia Tech

  • Rahul Kulkarni

    Materials and Structures Laboratory, Tokyo Institute of Technology, Jefferson Lab, 12000 Jefferson Avenue, MS 58, Suite 17, Newport News, VA 23606, VirginiaTech, Department of Physics, University of South Alabama, New York University, University of Tennessee Knoxville, Georgia College, North Georgia College \& State Univ., North Carolina Central University, TUNL, James Madison University, Physics Department, Hollins University; JQI, University of Aarhus, University of Tennessee, UNC at Asheville, The College of New Jersey, CERN, Florida Institute of Technology, Mechanical Engineering Department, University of New Mexico, Department of Physics, Florida State University, JINR, Vanderbilt, Tsinghua University, LBNL, Vanderbilt and LBNL, Vanderbilt University, Vanderbilt University, Tsinghua University, Vanderbilt University, LBNL, NBPHS, Vanderbilt University, Dept. of Physics and Astronomy - James Madison University, National High Magnetic Field Laboratory, U. of South Alabama Dept. of Chemistry, U. of South Alabama Dept. of Physics, Ohio State University, Wright State University, Engineering Science and Mechanics, Virginia Tech, US, Department of Nanobio Materials and Electronics, GIST, Republic of Korea, Department of Physics, Virginia Tech

  • R.E. Sykora

    U. of South Alabama Dept. of Chemistry

  • A.P. Reyes

    National High Magnetic Field Laboratory

  • Rahul Kulkarni

    Materials and Structures Laboratory, Tokyo Institute of Technology, Jefferson Lab, 12000 Jefferson Avenue, MS 58, Suite 17, Newport News, VA 23606, VirginiaTech, Department of Physics, University of South Alabama, New York University, University of Tennessee Knoxville, Georgia College, North Georgia College \& State Univ., North Carolina Central University, TUNL, James Madison University, Physics Department, Hollins University; JQI, University of Aarhus, University of Tennessee, UNC at Asheville, The College of New Jersey, CERN, Florida Institute of Technology, Mechanical Engineering Department, University of New Mexico, Department of Physics, Florida State University, JINR, Vanderbilt, Tsinghua University, LBNL, Vanderbilt and LBNL, Vanderbilt University, Vanderbilt University, Tsinghua University, Vanderbilt University, LBNL, NBPHS, Vanderbilt University, Dept. of Physics and Astronomy - James Madison University, National High Magnetic Field Laboratory, U. of South Alabama Dept. of Chemistry, U. of South Alabama Dept. of Physics, Ohio State University, Wright State University, Engineering Science and Mechanics, Virginia Tech, US, Department of Nanobio Materials and Electronics, GIST, Republic of Korea, Department of Physics, Virginia Tech