Nonmonotonic conductivity change of C60 fullerene crystals under dynamic compression up to 300 kbar

ORAL

Abstract

In the present work the conductivity of fullerene C$_{60}$ crystals has been measured under smooth shock wave quasi-isentropic loading conditions up to 30 GPa at initial temperature T=293 K. Not monotone behavior of conductivity has been revealed under compression of crystal with pressure increasing: -at first conductivity grows by many orders then it falls very fast. Conductivity increasing is explained by decreasing of bandgap of C$_{60}$ under compression whereas conductivity decreasing can be explained on the assumption that the energy barrier of polymerization of C$_{60}$ reduces with pressure increasing approximately in the same measure as band-gap energy. Research is financially supported by the Russian foundation for basic research, the grant N 03-02-16322, the grant of the President of Russia NS 1938.2003.2, and program of basic researches of the Russian Academy of Science ``Thermophysics and mechanics of processes at high energy densities.''

Authors

  • Vladimir V. Avdonin

  • V.I. Postnov

  • D.V. Shakhray

  • K.L. Kagan

  • A.F. Shestakov

  • V.E. Fortov

    Institute of Chemical Physics, Moscow, Institute for High Energy Densities of Russian Academy of Sciences (IHED RAS), Institute for High Energy Density Physics RAS, IPCP RAS, Institute of Problem of Chemical Physics RAS

  • V.V. Kveder

  • R.K. Nikolaev

  • N.S. Sidorov

  • Y.A. Ossipyan

    Institute of Solid State Physics RAS