Phase Boundaries, Isotope Effect and Superconductivity of Lithium Under Hydrostatic Conditions

The large lattice dynamics of lithium, driven by its low atomic mass, result in energetically similar structures and significant isotope effects under pressure, posing challenges to current theoretical models. Above 20 GPa and at low temperatures, lithium's electronic properties deviate from simple metallic behavior, with superconductivity emerging in a complex, pressure-dependent manner alongside an unusual isotope effect. The structural phases of ⁷Li under these conditions are inconsistent across studies, and the structures of ⁶Li remain unexamined. These gaps limit our understanding of the effects of pressure on lithium's electronic properties and the role of quantum lattice effects in its structural behavior under pressure. Here, we integrate experimental and theoretical approaches to investigate low-temperature structural phase boundaries in lithium isotopes. We map the structural phase diagram of ⁷Li from 5 to 55 GPa and 15–75 K, identifying the sequence fcc → hR1 → cI16. A pronounced isotope effect is observed, with ⁶Li shifting the fcc → hR1 phase boundary to lower pressures at 15 K. Density functional theory calculations further clarify how these structural changes affect superconducting properties, particularly emphasizing the role of the fcc→hR1 transition in lithium's superconductivity. Our findings offer new insights into the unique behaviors of lithium isotopes under pressure.