Morphogenesis of Spin Cycloids in a Non-collinear Antiferromagnet

Pattern formation in spin systems with continuous-rotational symmetry (CRS) provides a powerful approach to study emergent complex magnetic phases and topological defects in condensed-matter physics. However, its understanding and correlation with unconventional magnetic order along with high-resolution nanoscale imaging is challenging. Here, we present the morphogenesis of spin cycloids at both the local and global scales within a single ferroelectric domain of (111)-oriented BiFeO₃ which is a multiferroic non-collinear antiferromagnet, resulting in formation of a glassy labyrinth pattern. We find that the domains of locally oriented cycloids are interconnected by an array of topological defects and exhibit isotropic energy landscape predicted by first-principles calculations. We propose that the CRS of spin-cycloid propagation directions within the (111) drives the formation of the labyrinthine pattern and the associated topological defects such as antiferromagnetic skyrmions. Unexpectedly, reversing the as-grown ferroelectric polarization from [-1-1-1] to [111] induces a magnetic phase transition, destroying the labyrinthine pattern and producing a deterministic non-volatile non cycloidal, uniformly magnetized state. These findings highlight that (111)-oriented BiFeO₃ is not only important for studying the fascinating subject of pattern formation but could also be utilized as an ideal platform for integrating novel topological defects in the field of antiferromagnetic spintronics.