Synthesis of a 'true' Weyl semimetal from a semiconductor, (Cr,Bi)<sub>2</sub>Te<sub>3</sub>

ORAL  · Invited

Abstract

New materials and quantum phases drive electronic, photonics and quantum technologies. The breakthrough synthesis of the semiconductor GaN in the early 1990s gave us the blue LED, used for lighting and power electronics [1]. What would it take for semimetals and topological materials to have such impact? In the case of Weyl semimetals, one problem is that our Weyl materials are not actually semimetals. An intense worldwide effort starting ~2014 to search all known crystalline materials for Weyl physics gave us TaAs [2], CoSi [3], Co2MnGa [4,5] and Co3Sn2S2 [6,7]. These materials all exhibit conventional metallic resistivity, hosting intrinsic, trivial conduction electrons which obscure the unique Weyl properties. We have now instead used molecular beam epitaxy to dope the topological semiconductor Bi2Te3 with ferromagnetic Cr [8,9]. We find that (Cr,Bi)2Te3 exhibits a record bulk anomalous Hall angle > 0.5 (the key figure of merit for a magnetic Weyl semimetal) along with non-metallic conductivity, sharply distinct from earlier Weyl materials and conventional ferromagnets. Together with theory, our experiments suggest that (Cr,Bi)2Te3 has a semimetallic Fermi surface composed of only two Weyl points, without irrelevant electronic states. Our design principle could be broadened to ‘true’ non-centrosymmetric Weyl semimetals and may serve as a bridge to commercial semiconductor technologies. Improving the crystalline quality should further increase the figure of merit, and could enable a richer exploration of Weyl light-matter interaction, non-linear response and applications to interconnects and THz generation/detection.

[1] I. Akasaki, H. Amano & S. Nakamura. Nobel Prize in Physics (2014)

[2] Su-Yang Xu, I.B. et al. Science 349, 613 (2015)

[3] D. S. Sanchez, I.B. et al. Nature 567, 500 (2019)

[4] I.B. et al. Nature 604, 647 (2022)

[5] I.B. et al. Science 365, 1278 (2019)

[6] Enke Liu et al. Nat. Phys. 14, 1125 (2018)

[7] I.B. et al. Phys. Rev. Lett. 127, 256403 (2021)

[8] Tokura, Yasuda and Tsukazaki, Nat. Rev. Phys. 1, 126 (2019)

[9] I.B. et al. Nature 637, 1078 (2025)

*This work was supported by JSPS KAKENHI 23H05431 (Y. Tokura), 24K17020 (Y.S.), 24H01607 (M.H.), 22H04958 (M. Kawasaki), 24H00197 (N.N.), 24H02231 (N.N.) and 23H01861 (M. Kawamura); and by JST FOREST JPMJFR2238 (M.H.).

Publication: Belopolski et al. Nature 637, 1078-1083 (2025).

Presenters

  • Ilya Belopolski

    • RIKEN

Authors

  • Ilya Belopolski

    • RIKEN
  • Ryota Watanabe

    • University of Tokyo
  • Yuki Sato

    • RIKEN Center for Emergent Matter Science (CEMS)
    • RIKEN
  • Ryutaro Yoshimi

    • Department of Advanced Materials Science, The University of Tokyo
    • The University of Tokyo
    • RIKEN
  • Minoru Kawamura

    • RIKEN Center for Emergent Matter Science (CEMS)
    • RIKEN
  • Soma Nagahama

    • The University of Tokyo
  • Max T Birch

    • RIKEN Center for Emergent Matter Science
    • RIKEN
    • RIKEN, CEMS
  • Lixuan Tai

    • University of California, Los Angeles
  • Yilin Zhao

    • Nanyang Technological University
  • Sen Shao

    • Nanyang Technological University
  • Yuanjun JIN

    • Nanyang Technological University
  • Yoshihiro Kato

    • University of Tokyo
  • Yoshihiro Okamura

    • The University of Tokyo
    • Univ of Tokyo
  • Xiao-Xiao Zhang

    • Huazhong University of Science and Technology
    • RIKEN
  • Yukako Fujishiro

    • RIKEN
  • Youtarou Takahashi

    • The University of Tokyo
    • University of Tokyo
  • Max Hirschberger

    • The University of Tokyo
    • University of Tokyo
  • Atsushi Tsukazaki

    • Department of Applied Physics and Quantum-Phase Electronics Center (QPEC), The University of Tokyo
    • The University of Tokyo
    • University of Tokyo
  • Kei S Takahashi

    • RIKEN Center for Emergent Matter Science (CEMS)
    • RIKEN
  • Ching-Kai Chiu

    • RIKEN
    • RIKEN iTHEMS
  • Guoqing Chang

    • Nanyang Technological University
  • Masashi Kawasaki

    • Univ of Tokyo, RIKEN CEMS
    • University of Tokyo
    • RIKEN Center for Emergent Matter Science (CEMS), Department of Applied Physics and Quantum-Phase Electronics Center (QPEC), The University of Tokyo
    • The University of Tokyo, RIKEN
  • Naoto Nagaosa

    • RIKEN
    • RIKEN Center for Emergent Matter Science
    • RIKEN, CEMS
  • Yoshinori Tokura

    • The University of Tokyo
    • Univ of Tokyo
    • RIKEN Center for Emergent Matter Science (CEMS), Tokyo College, the University of Tokyo
    • The University of Tokyo, RIKEN
    • University of Tokyo