Perovskites based Photon Counting X-ray Detectors

ORAL  · Invited

Abstract

Perovskite photon counting detectors have emerged as a promising technology due to their exceptional optoelectronic properties, including high absorption coefficients to visible light and also to ionization radiation, long carrier recombination lifetime, tunable bandgaps, and defect tolerance. These features enable high sensitivity, low dark noise, and excellent energy resolution, making them ideal for applications in medical imaging, high-energy physics, security screening, and astronomy. I will present our recent progress on improving optimizing crystal growth, reduce device noise by defects manipulation, for both scintillator readout and direct photon counting using semiconductors. I will first report how to move perovskite photon-counting detectors from a promising concept toward practical devices by demonstrating high-sensitivity, low-noise detectors that can operate even without external bias and rival commercial silicon photomultipliers for photon counting. A parallel thrust in our research addresses materials challenges—stability and defect engineering (including chemical treatments and defect-repair strategies) to reduce deep and shallow traps and extend device lifetime—helping translate lab devices toward robust, large-area and clinical/industrial applications.

*We thank financial support from National Institute of Biomedical Imaging and Bioengineering of the National Institutes of Health (NIH) under award number R01EB033439 and Defense Threat Reduction Agency (DTRA) under award no. HDTRA1-20-2-0002.

Publication: Defect Repairing in Lead Bromide Perovskite Single Crystals with Biasing and Bromine for X-ray Photon-counting Detectors
Mingze Li, Shaojie Wang, Allen Wood, Jason D. Yeager, Sergei P. Stepanoff, Jackson C. Adler, Zhifang Shi, Jian Wang, Zhijun Li, Douglas E. Wolfe and Jinsong Huang*, Nature Materials, https://doi.org/10.1038/s41563-025-02310-x
Surface-defect-passivation-enabled near-unity charge collection efficiency in bromide-based perovskite gamma-ray spectrum devices
Liang Zhao, Zhifang Shi, Ying Zhou, Xiaoming Wang, Yeming Xian, Yifan Dong, Obadiah Reid, Zhenyi Ni, Matthew C. Beard, Yanfa Yan*, and Jinsong Huang*, Nature Photonics, 2024, https://www.nature.com/articles/s41566-023-01356-0
High-yield growth of FACsPbBr3 single crystals with low defect density from mixed solvents for gamma-ray spectroscopy
Liang Zhao, Ying Zhou, Zhifang Shi, Zhenyi Ni, Mengru Wang, Ye Liu, and Jinsong Huang*, Nature Photonics, Volume 17 | April 2023 | 315–323, 10.1038/s41566-023-01154-8

Presenters

  • Jinsong Huang

    • University of North Carolina at Chapel Hill

Authors

  • Jinsong Huang

    • University of North Carolina at Chapel Hill