HgSe Semiconductor Nanoclusters in Zeolite

ORAL

Abstract

Changing the size of small (10-50 A) nanoclusters of semi-conductors modifies their optical, electronic, magnetic, thermodynamic, and photocatalytic properties. Therefore there are variety of potential electronic, photochemical and non-linear optical applications of these nanoclusters in the industry. Studying the atomic structures of these nanoclusters is necessary for an analysis of the transition from molecular to bulk semi-conductor properties. Our primary challenge has been to produce HgSe semiconductor nanoclusters with a precise, controllable and narrow size distribution. Since a zeolite framework constrains the size and shape of species encapsulated within a pore, we use zeolite pores to contain our nanoclusters. AXS (Anomalous X-ray Scattering) technique is used in combination with the PDF (atomic pair distribution function) technique to solve for the structure of the nanocluster. We use optical absorption measurements to determine the band gap of the cluster. Finally we intend to perform Raman Spectroscopy to complement our determination of local structure and to probe the electronic properties of the semiconductor nanoclusters.

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Authors

  • A.M. Milinda Abeykoon

    University of Houston

  • Nilanjan Das

    Dept. of Physics, ESFM-IPN, Mexico City, Dept. of Physics, The University of Texas at El Paso, Texas A\&M University, Southeast Missouri State University, Departamento de Fisica, FCEN, Universidad de Buenos Aires, Nunez, Argentina, Cyclotron Institute, Texas A\&M University, University of Houston, Denison U., Advanced Space Propulsion Laboratory, AdAstra Rocket Company, Texas Tech University, Department of Chemistry and Biochemistry, Texas State Unv. - San Marcos, Department of Physics, Texas State Unv. - San Marcos, Rice U., Texas State University - San Marcos, Freescale Semiconductor, Inc., Varian Semiconductor Equipment Associates, Gloucester, MA, University of North Texas, Denton, TX, National Insitute of Standards \& Technology, Gaithersburg, MD, James Madison University, Harrisonburg, VA, Texas A\&M University, College Station, TX, Hong Kong University of Science and Technology; Texas Center for Superconductivity and Advanced Materials, University of Houston, Texas Center for Superconductivity at the University of Houston, University of Houston, University of Idaho, Department of Physics, Istanbul Technical University, University of California at Davis, Physics Department, University of South Florida, FL 33620, Physics Department, Texas A\&M University, TX 77843, Center for Studies in Statistical Mechanics and Complex Systems, The University of Texas at Austin, Rice University, TcSUH, University of Houston, Lawrence Berkeley National Laboratory, Hong Kong University of Science and Technology, Institute of Solid State Physics, Bulgarian Academy of Sciences, Hong Kong University of Science and Technology; Texas Center for Superconductivity, University of Houston; Lawrence Berkeley National Laboratory, Texas Center for Superconductivity, University of Houston

  • Nilanjan Das

    Dept. of Physics, ESFM-IPN, Mexico City, Dept. of Physics, The University of Texas at El Paso, Texas A\&M University, Southeast Missouri State University, Departamento de Fisica, FCEN, Universidad de Buenos Aires, Nunez, Argentina, Cyclotron Institute, Texas A\&M University, University of Houston, Denison U., Advanced Space Propulsion Laboratory, AdAstra Rocket Company, Texas Tech University, Department of Chemistry and Biochemistry, Texas State Unv. - San Marcos, Department of Physics, Texas State Unv. - San Marcos, Rice U., Texas State University - San Marcos, Freescale Semiconductor, Inc., Varian Semiconductor Equipment Associates, Gloucester, MA, University of North Texas, Denton, TX, National Insitute of Standards \& Technology, Gaithersburg, MD, James Madison University, Harrisonburg, VA, Texas A\&M University, College Station, TX, Hong Kong University of Science and Technology; Texas Center for Superconductivity and Advanced Materials, University of Houston, Texas Center for Superconductivity at the University of Houston, University of Houston, University of Idaho, Department of Physics, Istanbul Technical University, University of California at Davis, Physics Department, University of South Florida, FL 33620, Physics Department, Texas A\&M University, TX 77843, Center for Studies in Statistical Mechanics and Complex Systems, The University of Texas at Austin, Rice University, TcSUH, University of Houston, Lawrence Berkeley National Laboratory, Hong Kong University of Science and Technology, Institute of Solid State Physics, Bulgarian Academy of Sciences, Hong Kong University of Science and Technology; Texas Center for Superconductivity, University of Houston; Lawrence Berkeley National Laboratory, Texas Center for Superconductivity, University of Houston

  • Nilanjan Das

    Dept. of Physics, ESFM-IPN, Mexico City, Dept. of Physics, The University of Texas at El Paso, Texas A\&M University, Southeast Missouri State University, Departamento de Fisica, FCEN, Universidad de Buenos Aires, Nunez, Argentina, Cyclotron Institute, Texas A\&M University, University of Houston, Denison U., Advanced Space Propulsion Laboratory, AdAstra Rocket Company, Texas Tech University, Department of Chemistry and Biochemistry, Texas State Unv. - San Marcos, Department of Physics, Texas State Unv. - San Marcos, Rice U., Texas State University - San Marcos, Freescale Semiconductor, Inc., Varian Semiconductor Equipment Associates, Gloucester, MA, University of North Texas, Denton, TX, National Insitute of Standards \& Technology, Gaithersburg, MD, James Madison University, Harrisonburg, VA, Texas A\&M University, College Station, TX, Hong Kong University of Science and Technology; Texas Center for Superconductivity and Advanced Materials, University of Houston, Texas Center for Superconductivity at the University of Houston, University of Houston, University of Idaho, Department of Physics, Istanbul Technical University, University of California at Davis, Physics Department, University of South Florida, FL 33620, Physics Department, Texas A\&M University, TX 77843, Center for Studies in Statistical Mechanics and Complex Systems, The University of Texas at Austin, Rice University, TcSUH, University of Houston, Lawrence Berkeley National Laboratory, Hong Kong University of Science and Technology, Institute of Solid State Physics, Bulgarian Academy of Sciences, Hong Kong University of Science and Technology; Texas Center for Superconductivity, University of Houston; Lawrence Berkeley National Laboratory, Texas Center for Superconductivity, University of Houston

  • Nilanjan Das

    Dept. of Physics, ESFM-IPN, Mexico City, Dept. of Physics, The University of Texas at El Paso, Texas A\&M University, Southeast Missouri State University, Departamento de Fisica, FCEN, Universidad de Buenos Aires, Nunez, Argentina, Cyclotron Institute, Texas A\&M University, University of Houston, Denison U., Advanced Space Propulsion Laboratory, AdAstra Rocket Company, Texas Tech University, Department of Chemistry and Biochemistry, Texas State Unv. - San Marcos, Department of Physics, Texas State Unv. - San Marcos, Rice U., Texas State University - San Marcos, Freescale Semiconductor, Inc., Varian Semiconductor Equipment Associates, Gloucester, MA, University of North Texas, Denton, TX, National Insitute of Standards \& Technology, Gaithersburg, MD, James Madison University, Harrisonburg, VA, Texas A\&M University, College Station, TX, Hong Kong University of Science and Technology; Texas Center for Superconductivity and Advanced Materials, University of Houston, Texas Center for Superconductivity at the University of Houston, University of Houston, University of Idaho, Department of Physics, Istanbul Technical University, University of California at Davis, Physics Department, University of South Florida, FL 33620, Physics Department, Texas A\&M University, TX 77843, Center for Studies in Statistical Mechanics and Complex Systems, The University of Texas at Austin, Rice University, TcSUH, University of Houston, Lawrence Berkeley National Laboratory, Hong Kong University of Science and Technology, Institute of Solid State Physics, Bulgarian Academy of Sciences, Hong Kong University of Science and Technology; Texas Center for Superconductivity, University of Houston; Lawrence Berkeley National Laboratory, Texas Center for Superconductivity, University of Houston

  • Nilanjan Das

    Dept. of Physics, ESFM-IPN, Mexico City, Dept. of Physics, The University of Texas at El Paso, Texas A\&M University, Southeast Missouri State University, Departamento de Fisica, FCEN, Universidad de Buenos Aires, Nunez, Argentina, Cyclotron Institute, Texas A\&M University, University of Houston, Denison U., Advanced Space Propulsion Laboratory, AdAstra Rocket Company, Texas Tech University, Department of Chemistry and Biochemistry, Texas State Unv. - San Marcos, Department of Physics, Texas State Unv. - San Marcos, Rice U., Texas State University - San Marcos, Freescale Semiconductor, Inc., Varian Semiconductor Equipment Associates, Gloucester, MA, University of North Texas, Denton, TX, National Insitute of Standards \& Technology, Gaithersburg, MD, James Madison University, Harrisonburg, VA, Texas A\&M University, College Station, TX, Hong Kong University of Science and Technology; Texas Center for Superconductivity and Advanced Materials, University of Houston, Texas Center for Superconductivity at the University of Houston, University of Houston, University of Idaho, Department of Physics, Istanbul Technical University, University of California at Davis, Physics Department, University of South Florida, FL 33620, Physics Department, Texas A\&M University, TX 77843, Center for Studies in Statistical Mechanics and Complex Systems, The University of Texas at Austin, Rice University, TcSUH, University of Houston, Lawrence Berkeley National Laboratory, Hong Kong University of Science and Technology, Institute of Solid State Physics, Bulgarian Academy of Sciences, Hong Kong University of Science and Technology; Texas Center for Superconductivity, University of Houston; Lawrence Berkeley National Laboratory, Texas Center for Superconductivity, University of Houston