Surface Defect States in Nanopowder ZnO

ORAL

Abstract

In our work we employed surface photovoltage (SPV) spectroscopy on a number of commercially available ZnO nanopowders to probe surface defect energies within the band gap, conduction vs. valence band nature of the defect-related transitions, as well as the surface photoresponse dynamics. SPV characterization was performed in ultra-high vacuum in situ with remote oxygen plasma treatments. Our experiments revealed a number of common spectral features related to surface states in the as-received and plasma-processed samples. Furthermore, we observed significant plasma-induced changes in the surface defect properties. Complementary ex situ photoluminescence measurements performed on the studied samples were correlated with the SPV results and demonstrated that our approach is efficient in detecting specific surface states in nanoscale ZnO specimens and in elucidating their nature.

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Authors

  • Yuri M. Strzhemechny

    Texas Christian University, Fort Worth, TX

  • Andrey Chabanov

    West Texas A\&M University, Rhodes College, Texas Woman's University, University of Texas at San Antonio, Texas A\&M University, Department of Physics, University of Texas at Arlington, Texas State University, Pajarito Scientific Corporation, Idaho National Laboratory, Duke University, UNC, Department of Chemistry, UTSA, Department of Physics and Astronomy, UTSA, The University of Texas at San Antonio, Harvar-Smithsonian Center for Astrophysics, University of New Mexico, Maria Mitchel Observatory, NRAO, University of Alabama, Trinity University, Department of Physics and Astronomy, University of Texas at San Antonio, San Antonio, Texas 78249, V. Alecsandri College, Bacau, Romania, University of Texas at Dallas, Argonne National Laboratory, Western Michigan University, Institute of Physics, UNAM, Mexico, University of North Texas - Chemistry, University of St. Thomas, SwRI San Antonio, Alan G. MacDiarmid NanoTech Institute, University of Texas at Dallas, Department of Electrical and Computer Engineering, University of Texas at Arlington, Department of Physics, University of Texas at Brownsville, SciPrint.org, The University of Texas at Austin, Georgia Tech, MIT, University of Tennessee, University of Michigan, ORNL, Texas A&M University-Commerce, University of Texas San Antonio, University of Texas at Brownsville, University of Dallas, Sternberg Astronomical Institute, SwRI, CU-Boulder, SwRI/UTSA, Southwest Research Institute, JILA, University of Colorado, Department of Physics, Texas A\&M University, Stephen F. Austin State University, Angelo State University, St. Mary's University, Physics Department, University of South Florida, CINVESTAV, Queretaro, Mexico, Department of Physics, UCSD, LANSCE, Los Alamos National Laboratory, Department of Physics and Astronomy, Texas A\&M University, Texas A\&M University: Department of Physics, Texas Christian University, Fort Worth, TX, Paschal High School, Fort Worth, TX, Tarleton State University, Stephenville, TX, Paine College, Augusta, GA, University of Houston, University of Texas at Arlington, IREAP, Department of Physics, University of Maryland, Air Force Research Laboratory, Institute for Quantum Studies and Department of Physics, Texas A\&M Universtity, College Station, Texas 77843, USA, Max-Planck Institut for Kernphysik, Saupfercheckweg 1,D-69117 Heidelberg, Germany, The National Center for Mathematics and Physics, P.O. Box 6086, KACST, Riyadh 11442, Saudi Arabia

  • Andrey Chabanov

    West Texas A\&M University, Rhodes College, Texas Woman's University, University of Texas at San Antonio, Texas A\&M University, Department of Physics, University of Texas at Arlington, Texas State University, Pajarito Scientific Corporation, Idaho National Laboratory, Duke University, UNC, Department of Chemistry, UTSA, Department of Physics and Astronomy, UTSA, The University of Texas at San Antonio, Harvar-Smithsonian Center for Astrophysics, University of New Mexico, Maria Mitchel Observatory, NRAO, University of Alabama, Trinity University, Department of Physics and Astronomy, University of Texas at San Antonio, San Antonio, Texas 78249, V. Alecsandri College, Bacau, Romania, University of Texas at Dallas, Argonne National Laboratory, Western Michigan University, Institute of Physics, UNAM, Mexico, University of North Texas - Chemistry, University of St. Thomas, SwRI San Antonio, Alan G. MacDiarmid NanoTech Institute, University of Texas at Dallas, Department of Electrical and Computer Engineering, University of Texas at Arlington, Department of Physics, University of Texas at Brownsville, SciPrint.org, The University of Texas at Austin, Georgia Tech, MIT, University of Tennessee, University of Michigan, ORNL, Texas A&M University-Commerce, University of Texas San Antonio, University of Texas at Brownsville, University of Dallas, Sternberg Astronomical Institute, SwRI, CU-Boulder, SwRI/UTSA, Southwest Research Institute, JILA, University of Colorado, Department of Physics, Texas A\&M University, Stephen F. Austin State University, Angelo State University, St. Mary's University, Physics Department, University of South Florida, CINVESTAV, Queretaro, Mexico, Department of Physics, UCSD, LANSCE, Los Alamos National Laboratory, Department of Physics and Astronomy, Texas A\&M University, Texas A\&M University: Department of Physics, Texas Christian University, Fort Worth, TX, Paschal High School, Fort Worth, TX, Tarleton State University, Stephenville, TX, Paine College, Augusta, GA, University of Houston, University of Texas at Arlington, IREAP, Department of Physics, University of Maryland, Air Force Research Laboratory, Institute for Quantum Studies and Department of Physics, Texas A\&M Universtity, College Station, Texas 77843, USA, Max-Planck Institut for Kernphysik, Saupfercheckweg 1,D-69117 Heidelberg, Germany, The National Center for Mathematics and Physics, P.O. Box 6086, KACST, Riyadh 11442, Saudi Arabia

  • Andrey Chabanov

    West Texas A\&M University, Rhodes College, Texas Woman's University, University of Texas at San Antonio, Texas A\&M University, Department of Physics, University of Texas at Arlington, Texas State University, Pajarito Scientific Corporation, Idaho National Laboratory, Duke University, UNC, Department of Chemistry, UTSA, Department of Physics and Astronomy, UTSA, The University of Texas at San Antonio, Harvar-Smithsonian Center for Astrophysics, University of New Mexico, Maria Mitchel Observatory, NRAO, University of Alabama, Trinity University, Department of Physics and Astronomy, University of Texas at San Antonio, San Antonio, Texas 78249, V. Alecsandri College, Bacau, Romania, University of Texas at Dallas, Argonne National Laboratory, Western Michigan University, Institute of Physics, UNAM, Mexico, University of North Texas - Chemistry, University of St. Thomas, SwRI San Antonio, Alan G. MacDiarmid NanoTech Institute, University of Texas at Dallas, Department of Electrical and Computer Engineering, University of Texas at Arlington, Department of Physics, University of Texas at Brownsville, SciPrint.org, The University of Texas at Austin, Georgia Tech, MIT, University of Tennessee, University of Michigan, ORNL, Texas A&M University-Commerce, University of Texas San Antonio, University of Texas at Brownsville, University of Dallas, Sternberg Astronomical Institute, SwRI, CU-Boulder, SwRI/UTSA, Southwest Research Institute, JILA, University of Colorado, Department of Physics, Texas A\&M University, Stephen F. Austin State University, Angelo State University, St. Mary's University, Physics Department, University of South Florida, CINVESTAV, Queretaro, Mexico, Department of Physics, UCSD, LANSCE, Los Alamos National Laboratory, Department of Physics and Astronomy, Texas A\&M University, Texas A\&M University: Department of Physics, Texas Christian University, Fort Worth, TX, Paschal High School, Fort Worth, TX, Tarleton State University, Stephenville, TX, Paine College, Augusta, GA, University of Houston, University of Texas at Arlington, IREAP, Department of Physics, University of Maryland, Air Force Research Laboratory, Institute for Quantum Studies and Department of Physics, Texas A\&M Universtity, College Station, Texas 77843, USA, Max-Planck Institut for Kernphysik, Saupfercheckweg 1,D-69117 Heidelberg, Germany, The National Center for Mathematics and Physics, P.O. Box 6086, KACST, Riyadh 11442, Saudi Arabia

  • Andrey Chabanov

    West Texas A\&M University, Rhodes College, Texas Woman's University, University of Texas at San Antonio, Texas A\&M University, Department of Physics, University of Texas at Arlington, Texas State University, Pajarito Scientific Corporation, Idaho National Laboratory, Duke University, UNC, Department of Chemistry, UTSA, Department of Physics and Astronomy, UTSA, The University of Texas at San Antonio, Harvar-Smithsonian Center for Astrophysics, University of New Mexico, Maria Mitchel Observatory, NRAO, University of Alabama, Trinity University, Department of Physics and Astronomy, University of Texas at San Antonio, San Antonio, Texas 78249, V. Alecsandri College, Bacau, Romania, University of Texas at Dallas, Argonne National Laboratory, Western Michigan University, Institute of Physics, UNAM, Mexico, University of North Texas - Chemistry, University of St. Thomas, SwRI San Antonio, Alan G. MacDiarmid NanoTech Institute, University of Texas at Dallas, Department of Electrical and Computer Engineering, University of Texas at Arlington, Department of Physics, University of Texas at Brownsville, SciPrint.org, The University of Texas at Austin, Georgia Tech, MIT, University of Tennessee, University of Michigan, ORNL, Texas A&M University-Commerce, University of Texas San Antonio, University of Texas at Brownsville, University of Dallas, Sternberg Astronomical Institute, SwRI, CU-Boulder, SwRI/UTSA, Southwest Research Institute, JILA, University of Colorado, Department of Physics, Texas A\&M University, Stephen F. Austin State University, Angelo State University, St. Mary's University, Physics Department, University of South Florida, CINVESTAV, Queretaro, Mexico, Department of Physics, UCSD, LANSCE, Los Alamos National Laboratory, Department of Physics and Astronomy, Texas A\&M University, Texas A\&M University: Department of Physics, Texas Christian University, Fort Worth, TX, Paschal High School, Fort Worth, TX, Tarleton State University, Stephenville, TX, Paine College, Augusta, GA, University of Houston, University of Texas at Arlington, IREAP, Department of Physics, University of Maryland, Air Force Research Laboratory, Institute for Quantum Studies and Department of Physics, Texas A\&M Universtity, College Station, Texas 77843, USA, Max-Planck Institut for Kernphysik, Saupfercheckweg 1,D-69117 Heidelberg, Germany, The National Center for Mathematics and Physics, P.O. Box 6086, KACST, Riyadh 11442, Saudi Arabia