Synthesis and Modification of Selected Rare Earth Nanoparticles

ORAL

Abstract

The goal of this research is to develop multifunctional nanomaterials for biological applications. The rare earth based nanoparticles (RENPs) have a potential to offer multiple modalities, which can be utilized in more comprehensive imaging of biological tissues. The specific goal was to modify the RENPs with clusters of transition metals in order to enhance their luminescence signal. The luminescent system based on the Er$^{3+}$:Y$_{2}$O$_{3}$ nanoparticles (NPs) was selected for the present studies. Several synthetic approaches were investigated in order to control the size and shape. The precipitation from homogenous solution using the urea decomposition yielded perfectly spherical Er$^{3+}$:Y$_{2}$O$_{3}$ with narrow size distribution and particle diameter of approximately 250 nm. The synthesis of Er$^{3+}$:Y$_{2}$O$_{3}$ using the microemulsion precipitation resulted in the irregularly shaped NPs with the average diameter of approximately 100 nm. The Er$^{3+}$:Y$_{2}$O$_{3}$ NPs surrounded by chitosan shell were modified with gold clusters in order to enhance their luminescence by metallic surface plasmon resonance. The luminescence of such [Er$^{3+}$:Y$_{2}$O$_{3}$][Chitosan-Au] hybrid NPs was investigated as a function of the gold content in the chitosan shell.

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Authors

  • Divya Guthikonda

    Department of Chemistry, UTSA

  • Andrey Chabanov

    West Texas A\&M University, Rhodes College, Texas Woman's University, University of Texas at San Antonio, Texas A\&M University, Department of Physics, University of Texas at Arlington, Texas State University, Pajarito Scientific Corporation, Idaho National Laboratory, Duke University, UNC, Department of Chemistry, UTSA, Department of Physics and Astronomy, UTSA, The University of Texas at San Antonio, Harvar-Smithsonian Center for Astrophysics, University of New Mexico, Maria Mitchel Observatory, NRAO, University of Alabama, Trinity University, Department of Physics and Astronomy, University of Texas at San Antonio, San Antonio, Texas 78249, V. Alecsandri College, Bacau, Romania, University of Texas at Dallas, Argonne National Laboratory, Western Michigan University, Institute of Physics, UNAM, Mexico, University of North Texas - Chemistry, University of St. Thomas, SwRI San Antonio, Alan G. MacDiarmid NanoTech Institute, University of Texas at Dallas, Department of Electrical and Computer Engineering, University of Texas at Arlington, Department of Physics, University of Texas at Brownsville, SciPrint.org, The University of Texas at Austin, Georgia Tech, MIT, University of Tennessee, University of Michigan, ORNL, Texas A&M University-Commerce, University of Texas San Antonio, University of Texas at Brownsville, University of Dallas, Sternberg Astronomical Institute, SwRI, CU-Boulder, SwRI/UTSA, Southwest Research Institute, JILA, University of Colorado, Department of Physics, Texas A\&M University, Stephen F. Austin State University, Angelo State University, St. Mary's University, Physics Department, University of South Florida, CINVESTAV, Queretaro, Mexico, Department of Physics, UCSD, LANSCE, Los Alamos National Laboratory, Department of Physics and Astronomy, Texas A\&M University, Texas A\&M University: Department of Physics, Texas Christian University, Fort Worth, TX, Paschal High School, Fort Worth, TX, Tarleton State University, Stephenville, TX, Paine College, Augusta, GA, University of Houston, University of Texas at Arlington, IREAP, Department of Physics, University of Maryland, Air Force Research Laboratory, Institute for Quantum Studies and Department of Physics, Texas A\&M Universtity, College Station, Texas 77843, USA, Max-Planck Institut for Kernphysik, Saupfercheckweg 1,D-69117 Heidelberg, Germany, The National Center for Mathematics and Physics, P.O. Box 6086, KACST, Riyadh 11442, Saudi Arabia

  • Andrey Chabanov

    West Texas A\&M University, Rhodes College, Texas Woman's University, University of Texas at San Antonio, Texas A\&M University, Department of Physics, University of Texas at Arlington, Texas State University, Pajarito Scientific Corporation, Idaho National Laboratory, Duke University, UNC, Department of Chemistry, UTSA, Department of Physics and Astronomy, UTSA, The University of Texas at San Antonio, Harvar-Smithsonian Center for Astrophysics, University of New Mexico, Maria Mitchel Observatory, NRAO, University of Alabama, Trinity University, Department of Physics and Astronomy, University of Texas at San Antonio, San Antonio, Texas 78249, V. Alecsandri College, Bacau, Romania, University of Texas at Dallas, Argonne National Laboratory, Western Michigan University, Institute of Physics, UNAM, Mexico, University of North Texas - Chemistry, University of St. Thomas, SwRI San Antonio, Alan G. MacDiarmid NanoTech Institute, University of Texas at Dallas, Department of Electrical and Computer Engineering, University of Texas at Arlington, Department of Physics, University of Texas at Brownsville, SciPrint.org, The University of Texas at Austin, Georgia Tech, MIT, University of Tennessee, University of Michigan, ORNL, Texas A&M University-Commerce, University of Texas San Antonio, University of Texas at Brownsville, University of Dallas, Sternberg Astronomical Institute, SwRI, CU-Boulder, SwRI/UTSA, Southwest Research Institute, JILA, University of Colorado, Department of Physics, Texas A\&M University, Stephen F. Austin State University, Angelo State University, St. Mary's University, Physics Department, University of South Florida, CINVESTAV, Queretaro, Mexico, Department of Physics, UCSD, LANSCE, Los Alamos National Laboratory, Department of Physics and Astronomy, Texas A\&M University, Texas A\&M University: Department of Physics, Texas Christian University, Fort Worth, TX, Paschal High School, Fort Worth, TX, Tarleton State University, Stephenville, TX, Paine College, Augusta, GA, University of Houston, University of Texas at Arlington, IREAP, Department of Physics, University of Maryland, Air Force Research Laboratory, Institute for Quantum Studies and Department of Physics, Texas A\&M Universtity, College Station, Texas 77843, USA, Max-Planck Institut for Kernphysik, Saupfercheckweg 1,D-69117 Heidelberg, Germany, The National Center for Mathematics and Physics, P.O. Box 6086, KACST, Riyadh 11442, Saudi Arabia

  • Andrey Chabanov

    West Texas A\&M University, Rhodes College, Texas Woman's University, University of Texas at San Antonio, Texas A\&M University, Department of Physics, University of Texas at Arlington, Texas State University, Pajarito Scientific Corporation, Idaho National Laboratory, Duke University, UNC, Department of Chemistry, UTSA, Department of Physics and Astronomy, UTSA, The University of Texas at San Antonio, Harvar-Smithsonian Center for Astrophysics, University of New Mexico, Maria Mitchel Observatory, NRAO, University of Alabama, Trinity University, Department of Physics and Astronomy, University of Texas at San Antonio, San Antonio, Texas 78249, V. Alecsandri College, Bacau, Romania, University of Texas at Dallas, Argonne National Laboratory, Western Michigan University, Institute of Physics, UNAM, Mexico, University of North Texas - Chemistry, University of St. Thomas, SwRI San Antonio, Alan G. MacDiarmid NanoTech Institute, University of Texas at Dallas, Department of Electrical and Computer Engineering, University of Texas at Arlington, Department of Physics, University of Texas at Brownsville, SciPrint.org, The University of Texas at Austin, Georgia Tech, MIT, University of Tennessee, University of Michigan, ORNL, Texas A&M University-Commerce, University of Texas San Antonio, University of Texas at Brownsville, University of Dallas, Sternberg Astronomical Institute, SwRI, CU-Boulder, SwRI/UTSA, Southwest Research Institute, JILA, University of Colorado, Department of Physics, Texas A\&M University, Stephen F. Austin State University, Angelo State University, St. Mary's University, Physics Department, University of South Florida, CINVESTAV, Queretaro, Mexico, Department of Physics, UCSD, LANSCE, Los Alamos National Laboratory, Department of Physics and Astronomy, Texas A\&M University, Texas A\&M University: Department of Physics, Texas Christian University, Fort Worth, TX, Paschal High School, Fort Worth, TX, Tarleton State University, Stephenville, TX, Paine College, Augusta, GA, University of Houston, University of Texas at Arlington, IREAP, Department of Physics, University of Maryland, Air Force Research Laboratory, Institute for Quantum Studies and Department of Physics, Texas A\&M Universtity, College Station, Texas 77843, USA, Max-Planck Institut for Kernphysik, Saupfercheckweg 1,D-69117 Heidelberg, Germany, The National Center for Mathematics and Physics, P.O. Box 6086, KACST, Riyadh 11442, Saudi Arabia

  • Andrey Chabanov

    West Texas A\&M University, Rhodes College, Texas Woman's University, University of Texas at San Antonio, Texas A\&M University, Department of Physics, University of Texas at Arlington, Texas State University, Pajarito Scientific Corporation, Idaho National Laboratory, Duke University, UNC, Department of Chemistry, UTSA, Department of Physics and Astronomy, UTSA, The University of Texas at San Antonio, Harvar-Smithsonian Center for Astrophysics, University of New Mexico, Maria Mitchel Observatory, NRAO, University of Alabama, Trinity University, Department of Physics and Astronomy, University of Texas at San Antonio, San Antonio, Texas 78249, V. Alecsandri College, Bacau, Romania, University of Texas at Dallas, Argonne National Laboratory, Western Michigan University, Institute of Physics, UNAM, Mexico, University of North Texas - Chemistry, University of St. Thomas, SwRI San Antonio, Alan G. MacDiarmid NanoTech Institute, University of Texas at Dallas, Department of Electrical and Computer Engineering, University of Texas at Arlington, Department of Physics, University of Texas at Brownsville, SciPrint.org, The University of Texas at Austin, Georgia Tech, MIT, University of Tennessee, University of Michigan, ORNL, Texas A&M University-Commerce, University of Texas San Antonio, University of Texas at Brownsville, University of Dallas, Sternberg Astronomical Institute, SwRI, CU-Boulder, SwRI/UTSA, Southwest Research Institute, JILA, University of Colorado, Department of Physics, Texas A\&M University, Stephen F. Austin State University, Angelo State University, St. Mary's University, Physics Department, University of South Florida, CINVESTAV, Queretaro, Mexico, Department of Physics, UCSD, LANSCE, Los Alamos National Laboratory, Department of Physics and Astronomy, Texas A\&M University, Texas A\&M University: Department of Physics, Texas Christian University, Fort Worth, TX, Paschal High School, Fort Worth, TX, Tarleton State University, Stephenville, TX, Paine College, Augusta, GA, University of Houston, University of Texas at Arlington, IREAP, Department of Physics, University of Maryland, Air Force Research Laboratory, Institute for Quantum Studies and Department of Physics, Texas A\&M Universtity, College Station, Texas 77843, USA, Max-Planck Institut for Kernphysik, Saupfercheckweg 1,D-69117 Heidelberg, Germany, The National Center for Mathematics and Physics, P.O. Box 6086, KACST, Riyadh 11442, Saudi Arabia