Spectroscopic analysis of gas separated from liquid

ORAL

Abstract

After the Deepwater Horizon oil spill, large concentrations of methane were observed dissolved in the Gulf of Mexico corresponding to a huge release of methane along with the discharge of oil from the site. It has been proposed that quantifying the amount of released methane could help quantify the magnitude of such a spill. We propose to build a system for extracting dissolved trace gasses from collected sea water samples that is capable of operating on board a research vessel. This system will enable on-site analysis of gas content without the need to transport large volumes of water samples back to the laboratory. The system is designed to continuously circulate a sample volume of water through a membrane filter that will extract dissolved gasses into an evacuated collection cylinder. The extracted gasses can then be analyzed on-site with infrared cavity ringdown spectroscopy. We present our initial results on the gas-liquid separation and on the ringdown spectroscopy of methane. The high sensitivity cavity ringdown spectrometer enables isotopic analysis of $^{13}$C, which can also serve to differentiate between carbon sources of natural and anthropogenic sources.

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Authors

  • James Bounds

    Department of Physics, Texas A\&M University, College Station, TX 77845

  • Darren Depoy

    University of Michigan, Univeristy of Michigan, Texas A\&M University, UC Riverside, University of Massachusetts, STScI, NOAO, University of Texas, Cyclotron Institute, Texas A\&M University, ENEA, Italy, INFN, Italy, University of Texas at Austin, TX, Cyclotron Institute, TAMU, TX, Cyclotron Institute TAMU, TX, Cyclotron Institute - Texas A\&M University, Texas A\&M Univ, Texas A\&M University, Baylor University, Department of Physics and Astronomy, Texas A\&M University, College Station, Texas, School of Materials Science and Engineering, Shanghai Jiaotong University, Shanghai, 200240, China, Department of Materials Science and Engineering, Texas A\&M University, College Station, Texas, Department of Mechanical Engineering, Texas A\&M University, College Station, Texas, Texas State University, University of Texas at Arlington, Lawrence Berkeley National Laboratory, DESY, Department of Physics and Astronomy, Texas A\&M University, Department of Physics, Syracuse University, Department of Physics and Astronomy, Vanderbilt University, Texas A\&M University, Princeton University and Baylor University, Texas A\&M Univ at Qatar, Kazan Federal University, Max Planck Institute for Nuclear Physics, Institue for Quantum Science and Engineering (IQSE) and Department of Physics \& Astronomy, Texas A\&M University, College Station, Texas 77843, USA, MIT, Sandia National Laboratories, Albuquerque, New Mexico, Postgrad, ORNL, Muons Inc., Texas Lutheran University, West Virginia University, Lawrence Livermore National Laboratory, University of Kentucky, US Naval Academy, University of Dallas, U.S. Naval Academy, Univ of Texas, Arlington, Department of Physics, Texas A\&M University, College Station, TX 77845, Science and Petroleum Departments, Texas A\&M University in Qatar, Doha, Qatar, Rice University, Houston, Texas, USA, Department of Physics, Texas State University, Florida A\&M University, Texas A\&M University in Qatar, Doha, Qatar, Physics and Astronomy Dept., TCU, Geology Dept., TCU, Colorado College, University of Texas at El Paso, University of Texas at Brownsville, Rochester Institute of Technology, Baylor University, Texas A\&M, Princeton University, Baylor University, Princeton University, Texas A\&M University, Materials Science and Engineering and Department of Physics and Astronomy, Texas A\&M University; WPI-AIMR, Tohoku University, Japan, WPI-AIMR, Tohoku University, Department of Chemistry, Texas A\&M University, Materials Science and Engineering and Department of Physics and Astronomy, Texas A\&M University, WPI-AIMR, Tohoku University, Japan, Department of Physics and Astronomy, Texas A\&M University, College Station, Texas 77843, USA, Department of Physics and Astronomy, Texas A\&M University and WPI-Advanced Institute for Materials Research, Tohoku University, Japan, University of Texas at Austin, Center for Nonlinear Dynamics and Department of Physics, The University of Texas at Austin, JILA, NIST, Department of Physics and Astronomy, Texas A\&M University and Institute for Quantum Studies and Engineering, College Station, TX 77843-4242, USA, Institute of Applied Physics of the Russian Academy of Sciences, 46 Ulyanov street, Nizhny Novgorod 603950, Russia, Department of Physics, University of Texas at Austin, Rice University, Texas A&M University

  • Darren Depoy

    University of Michigan, Univeristy of Michigan, Texas A\&M University, UC Riverside, University of Massachusetts, STScI, NOAO, University of Texas, Cyclotron Institute, Texas A\&M University, ENEA, Italy, INFN, Italy, University of Texas at Austin, TX, Cyclotron Institute, TAMU, TX, Cyclotron Institute TAMU, TX, Cyclotron Institute - Texas A\&M University, Texas A\&M Univ, Texas A\&M University, Baylor University, Department of Physics and Astronomy, Texas A\&M University, College Station, Texas, School of Materials Science and Engineering, Shanghai Jiaotong University, Shanghai, 200240, China, Department of Materials Science and Engineering, Texas A\&M University, College Station, Texas, Department of Mechanical Engineering, Texas A\&M University, College Station, Texas, Texas State University, University of Texas at Arlington, Lawrence Berkeley National Laboratory, DESY, Department of Physics and Astronomy, Texas A\&M University, Department of Physics, Syracuse University, Department of Physics and Astronomy, Vanderbilt University, Texas A\&M University, Princeton University and Baylor University, Texas A\&M Univ at Qatar, Kazan Federal University, Max Planck Institute for Nuclear Physics, Institue for Quantum Science and Engineering (IQSE) and Department of Physics \& Astronomy, Texas A\&M University, College Station, Texas 77843, USA, MIT, Sandia National Laboratories, Albuquerque, New Mexico, Postgrad, ORNL, Muons Inc., Texas Lutheran University, West Virginia University, Lawrence Livermore National Laboratory, University of Kentucky, US Naval Academy, University of Dallas, U.S. Naval Academy, Univ of Texas, Arlington, Department of Physics, Texas A\&M University, College Station, TX 77845, Science and Petroleum Departments, Texas A\&M University in Qatar, Doha, Qatar, Rice University, Houston, Texas, USA, Department of Physics, Texas State University, Florida A\&M University, Texas A\&M University in Qatar, Doha, Qatar, Physics and Astronomy Dept., TCU, Geology Dept., TCU, Colorado College, University of Texas at El Paso, University of Texas at Brownsville, Rochester Institute of Technology, Baylor University, Texas A\&M, Princeton University, Baylor University, Princeton University, Texas A\&M University, Materials Science and Engineering and Department of Physics and Astronomy, Texas A\&M University; WPI-AIMR, Tohoku University, Japan, WPI-AIMR, Tohoku University, Department of Chemistry, Texas A\&M University, Materials Science and Engineering and Department of Physics and Astronomy, Texas A\&M University, WPI-AIMR, Tohoku University, Japan, Department of Physics and Astronomy, Texas A\&M University, College Station, Texas 77843, USA, Department of Physics and Astronomy, Texas A\&M University and WPI-Advanced Institute for Materials Research, Tohoku University, Japan, University of Texas at Austin, Center for Nonlinear Dynamics and Department of Physics, The University of Texas at Austin, JILA, NIST, Department of Physics and Astronomy, Texas A\&M University and Institute for Quantum Studies and Engineering, College Station, TX 77843-4242, USA, Institute of Applied Physics of the Russian Academy of Sciences, 46 Ulyanov street, Nizhny Novgorod 603950, Russia, Department of Physics, University of Texas at Austin, Rice University, Texas A&M University

  • Darren Depoy

    University of Michigan, Univeristy of Michigan, Texas A\&M University, UC Riverside, University of Massachusetts, STScI, NOAO, University of Texas, Cyclotron Institute, Texas A\&M University, ENEA, Italy, INFN, Italy, University of Texas at Austin, TX, Cyclotron Institute, TAMU, TX, Cyclotron Institute TAMU, TX, Cyclotron Institute - Texas A\&M University, Texas A\&M Univ, Texas A\&M University, Baylor University, Department of Physics and Astronomy, Texas A\&M University, College Station, Texas, School of Materials Science and Engineering, Shanghai Jiaotong University, Shanghai, 200240, China, Department of Materials Science and Engineering, Texas A\&M University, College Station, Texas, Department of Mechanical Engineering, Texas A\&M University, College Station, Texas, Texas State University, University of Texas at Arlington, Lawrence Berkeley National Laboratory, DESY, Department of Physics and Astronomy, Texas A\&M University, Department of Physics, Syracuse University, Department of Physics and Astronomy, Vanderbilt University, Texas A\&M University, Princeton University and Baylor University, Texas A\&M Univ at Qatar, Kazan Federal University, Max Planck Institute for Nuclear Physics, Institue for Quantum Science and Engineering (IQSE) and Department of Physics \& Astronomy, Texas A\&M University, College Station, Texas 77843, USA, MIT, Sandia National Laboratories, Albuquerque, New Mexico, Postgrad, ORNL, Muons Inc., Texas Lutheran University, West Virginia University, Lawrence Livermore National Laboratory, University of Kentucky, US Naval Academy, University of Dallas, U.S. Naval Academy, Univ of Texas, Arlington, Department of Physics, Texas A\&M University, College Station, TX 77845, Science and Petroleum Departments, Texas A\&M University in Qatar, Doha, Qatar, Rice University, Houston, Texas, USA, Department of Physics, Texas State University, Florida A\&M University, Texas A\&M University in Qatar, Doha, Qatar, Physics and Astronomy Dept., TCU, Geology Dept., TCU, Colorado College, University of Texas at El Paso, University of Texas at Brownsville, Rochester Institute of Technology, Baylor University, Texas A\&M, Princeton University, Baylor University, Princeton University, Texas A\&M University, Materials Science and Engineering and Department of Physics and Astronomy, Texas A\&M University; WPI-AIMR, Tohoku University, Japan, WPI-AIMR, Tohoku University, Department of Chemistry, Texas A\&M University, Materials Science and Engineering and Department of Physics and Astronomy, Texas A\&M University, WPI-AIMR, Tohoku University, Japan, Department of Physics and Astronomy, Texas A\&M University, College Station, Texas 77843, USA, Department of Physics and Astronomy, Texas A\&M University and WPI-Advanced Institute for Materials Research, Tohoku University, Japan, University of Texas at Austin, Center for Nonlinear Dynamics and Department of Physics, The University of Texas at Austin, JILA, NIST, Department of Physics and Astronomy, Texas A\&M University and Institute for Quantum Studies and Engineering, College Station, TX 77843-4242, USA, Institute of Applied Physics of the Russian Academy of Sciences, 46 Ulyanov street, Nizhny Novgorod 603950, Russia, Department of Physics, University of Texas at Austin, Rice University, Texas A&M University

  • Darren Depoy

    University of Michigan, Univeristy of Michigan, Texas A\&M University, UC Riverside, University of Massachusetts, STScI, NOAO, University of Texas, Cyclotron Institute, Texas A\&M University, ENEA, Italy, INFN, Italy, University of Texas at Austin, TX, Cyclotron Institute, TAMU, TX, Cyclotron Institute TAMU, TX, Cyclotron Institute - Texas A\&M University, Texas A\&M Univ, Texas A\&M University, Baylor University, Department of Physics and Astronomy, Texas A\&M University, College Station, Texas, School of Materials Science and Engineering, Shanghai Jiaotong University, Shanghai, 200240, China, Department of Materials Science and Engineering, Texas A\&M University, College Station, Texas, Department of Mechanical Engineering, Texas A\&M University, College Station, Texas, Texas State University, University of Texas at Arlington, Lawrence Berkeley National Laboratory, DESY, Department of Physics and Astronomy, Texas A\&M University, Department of Physics, Syracuse University, Department of Physics and Astronomy, Vanderbilt University, Texas A\&M University, Princeton University and Baylor University, Texas A\&M Univ at Qatar, Kazan Federal University, Max Planck Institute for Nuclear Physics, Institue for Quantum Science and Engineering (IQSE) and Department of Physics \& Astronomy, Texas A\&M University, College Station, Texas 77843, USA, MIT, Sandia National Laboratories, Albuquerque, New Mexico, Postgrad, ORNL, Muons Inc., Texas Lutheran University, West Virginia University, Lawrence Livermore National Laboratory, University of Kentucky, US Naval Academy, University of Dallas, U.S. Naval Academy, Univ of Texas, Arlington, Department of Physics, Texas A\&M University, College Station, TX 77845, Science and Petroleum Departments, Texas A\&M University in Qatar, Doha, Qatar, Rice University, Houston, Texas, USA, Department of Physics, Texas State University, Florida A\&M University, Texas A\&M University in Qatar, Doha, Qatar, Physics and Astronomy Dept., TCU, Geology Dept., TCU, Colorado College, University of Texas at El Paso, University of Texas at Brownsville, Rochester Institute of Technology, Baylor University, Texas A\&M, Princeton University, Baylor University, Princeton University, Texas A\&M University, Materials Science and Engineering and Department of Physics and Astronomy, Texas A\&M University; WPI-AIMR, Tohoku University, Japan, WPI-AIMR, Tohoku University, Department of Chemistry, Texas A\&M University, Materials Science and Engineering and Department of Physics and Astronomy, Texas A\&M University, WPI-AIMR, Tohoku University, Japan, Department of Physics and Astronomy, Texas A\&M University, College Station, Texas 77843, USA, Department of Physics and Astronomy, Texas A\&M University and WPI-Advanced Institute for Materials Research, Tohoku University, Japan, University of Texas at Austin, Center for Nonlinear Dynamics and Department of Physics, The University of Texas at Austin, JILA, NIST, Department of Physics and Astronomy, Texas A\&M University and Institute for Quantum Studies and Engineering, College Station, TX 77843-4242, USA, Institute of Applied Physics of the Russian Academy of Sciences, 46 Ulyanov street, Nizhny Novgorod 603950, Russia, Department of Physics, University of Texas at Austin, Rice University, Texas A&M University

  • Darren Depoy

    University of Michigan, Univeristy of Michigan, Texas A\&M University, UC Riverside, University of Massachusetts, STScI, NOAO, University of Texas, Cyclotron Institute, Texas A\&M University, ENEA, Italy, INFN, Italy, University of Texas at Austin, TX, Cyclotron Institute, TAMU, TX, Cyclotron Institute TAMU, TX, Cyclotron Institute - Texas A\&M University, Texas A\&M Univ, Texas A\&M University, Baylor University, Department of Physics and Astronomy, Texas A\&M University, College Station, Texas, School of Materials Science and Engineering, Shanghai Jiaotong University, Shanghai, 200240, China, Department of Materials Science and Engineering, Texas A\&M University, College Station, Texas, Department of Mechanical Engineering, Texas A\&M University, College Station, Texas, Texas State University, University of Texas at Arlington, Lawrence Berkeley National Laboratory, DESY, Department of Physics and Astronomy, Texas A\&M University, Department of Physics, Syracuse University, Department of Physics and Astronomy, Vanderbilt University, Texas A\&M University, Princeton University and Baylor University, Texas A\&M Univ at Qatar, Kazan Federal University, Max Planck Institute for Nuclear Physics, Institue for Quantum Science and Engineering (IQSE) and Department of Physics \& Astronomy, Texas A\&M University, College Station, Texas 77843, USA, MIT, Sandia National Laboratories, Albuquerque, New Mexico, Postgrad, ORNL, Muons Inc., Texas Lutheran University, West Virginia University, Lawrence Livermore National Laboratory, University of Kentucky, US Naval Academy, University of Dallas, U.S. Naval Academy, Univ of Texas, Arlington, Department of Physics, Texas A\&M University, College Station, TX 77845, Science and Petroleum Departments, Texas A\&M University in Qatar, Doha, Qatar, Rice University, Houston, Texas, USA, Department of Physics, Texas State University, Florida A\&M University, Texas A\&M University in Qatar, Doha, Qatar, Physics and Astronomy Dept., TCU, Geology Dept., TCU, Colorado College, University of Texas at El Paso, University of Texas at Brownsville, Rochester Institute of Technology, Baylor University, Texas A\&M, Princeton University, Baylor University, Princeton University, Texas A\&M University, Materials Science and Engineering and Department of Physics and Astronomy, Texas A\&M University; WPI-AIMR, Tohoku University, Japan, WPI-AIMR, Tohoku University, Department of Chemistry, Texas A\&M University, Materials Science and Engineering and Department of Physics and Astronomy, Texas A\&M University, WPI-AIMR, Tohoku University, Japan, Department of Physics and Astronomy, Texas A\&M University, College Station, Texas 77843, USA, Department of Physics and Astronomy, Texas A\&M University and WPI-Advanced Institute for Materials Research, Tohoku University, Japan, University of Texas at Austin, Center for Nonlinear Dynamics and Department of Physics, The University of Texas at Austin, JILA, NIST, Department of Physics and Astronomy, Texas A\&M University and Institute for Quantum Studies and Engineering, College Station, TX 77843-4242, USA, Institute of Applied Physics of the Russian Academy of Sciences, 46 Ulyanov street, Nizhny Novgorod 603950, Russia, Department of Physics, University of Texas at Austin, Rice University, Texas A&M University