Relativistic all-order calculations of Th, Th$^{+}$ and Th$^{2+}$ atomic properties

POSTER

Abstract

Excitation energies, term designations, and $g$-factors of Th, Th$^{+}$ and Th$^{2+}$ are determined using a relativistic hybrid configuration interaction (CI) + all-order approach that combines configuration interaction and linearized coupled-cluster methods. The results are compared with other theory and experiment where available. Good agreement with experiment was found even for neutral Th owing to all-order treatment of the dominant correlation corrections and sufficient saturation of the configuration space. We find some ``vanishing'' $g$-factors, similar to those known in lanthanide spectra. Reduced matrix elements, oscillator strengths, transition rates, and lifetimes are determined for Th$^{2+}$. To estimate the uncertainties of our results, we compared our values with the available experimental lifetimes for higher $5f7p\ ^3G_{4}$, $7s7p\ ^3P_{0}$, $7s7p\ ^3P_{1}$, and $6d7p\ ^3F_{4}$ levels of Th$^{2+}$. These calculations provide a benchmark test of the CI+all-order method for heavy systems with several valence electrons and yield recommended values for transition rates and lifetimes of Th$^{2+}$.

Authors

  • Ulyana Safronova

    University of Nevada, Reno

  • Marianna Safronova

    University of Delaware and JQI, NIST and the University of Maryland, University of Delaware and Joint Quantum Institute

  • Charles W. Clark

    Joint Quantum Institute, NIST and the University of Maryland, JQI, NIST and the University of Maryland